Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Phase Transition and Approximated Integral Equation for Radial Distribution Function

  • Yoon, Byoung-Jip (Department of Chemistry, Kangreung National University) ;
  • Jhon, Mu-Shik (Department of Chemistry, Korea Advanced Institute of Science and Technology)
  • Published : 1986.02.20
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Abstract

A reduced condition for liquid-gas phase transition from the singularity of compressibility is derived using diagrammatic approach and is examined in the hard sphere system. The condition turns out that the Percus-Yevick and the Hyper-Netted-Chain approximation never conceive the idea of phase transition, and explains that the liquid-gas transition does not exist in hard sphere system. The solid-fluid transition is considered on the viewpoint of correlation function and diagrammatic analysis.

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