Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Lead Tolerance of Noble Metal Catalysts for CO Oxidation

  • Chang, Tu-Won (Inorganic Chemistry Laboratory, Korea Advanced Institute of Science and Technology) ;
  • Sohn, Youn-Soo (Inorganic Chemistry Laboratory, Korea Advanced Institute of Science and Technology)
  • Published : 1986.02.20
Download PDF
⟨ Previous Next ⟩

Abstract

Lead tolerance of $Pt/Al_2O_3$ catalysts was evaluated for CO oxidation depending on the properties of the alumina supports and base metals added as promoter. Among the four different alumina supports, the support with a large macropore volume (0.45 cc/g) and 5% Ce has shown the best resistence to lead poisoning. Most of the base metals added to the Pt-catalysts were found to be ineffective for improving lead resistence, but boron has shown an excellent lead tolerence, although it decreases the initial catalytic activity.

Keywords

References

  1. Advances in Catalysis v.27 M. Shelef;K. Otto;N. Otto
  2. Advances in Chemistry Series v.143 G. Acres;B. Cooper;E. Shutt;B. Malerbi
  3. Prog. Energy Combust. Sci. v.6 J. T. Kummer
  4. Advances in Chemistry Series v.143 R.L. Klimisch;J.C. Summers;J.C. Schlatter
  5. J. Catal. v.37 L. Hegedus;K. Baron
  6. Japan Kokai, 76-34891, 76-22694 M. Oshimura
  7. J. Catal. v.58 J.C. Summers;S.A. Ausen
  8. U.S.Pat. 4,157,316 C.E. Thomson;J.J. Mooney;C.D. Keith;W.A. Mannion
  9. Nature v.269 G. Croft;M.J. Fuller
  10. U.S.Pat. 3,619,127 R.H. Haas
  11. Japan Kokai 74-34493 T. Sakano;K. Fujiyame
  12. Japan Kokai 74-34493 T. Sakano;K. Fujiyame
  13. U.S.Pat. 3,455,843 W.S. Briggs
  14. Japan Kokai, 78-118289 K. Nishimoto;S. Yokoyama;T. Sera
  15. U.S.Pat. 3,388,077 J. Hoekstra
  16. Catalyst Deactivation B. Delmon(ed.);G.F. Froment(ed.)

Cited by

  1. Study of CO Oxidation on Well-Characterized Pt-Ru/C Electrocatalysts Having Different Composition vol.31, pp.1, 1986, https://doi.org/10.5012/bkcs.2010.31.01.151