A Study on Stabilized CdS-CdSe Red Stain A Study on Zircon Cadmium Sulphoselenide Stain

안정화 CdS-CdSe계 채료에 관한 연구 제2보$ ZrSiO_4-Cd(S_xS_{1-x})$ 의 합성

  • 이종근 (한양대학교 무기재료공학과) ;
  • 김종옥 (한양대학교 무기재료공학과)
  • Published : 1986.04.01

Abstract

The synthetic conditions of $ ZrSiO_4-Cd(S_xS_{1-x})$ stains from CdS, Se, $SiO_2$ , 4ZrO_2$ and Lif were investigated and the colors were examined. Colors of the stains prepared were yellow orange red pink ruby and violet in relation to both the content of CdS-Se in $ZrSiO_4$ and firing temperature. Colors of these series stains were thermally stabilized probably by the structural stability of zirconium silicate. Furthermore by the result of X-ray diffraction analysis it is assumed that color of the zircon cadmium sulphoselenide $ ZrSiO_4-Cd(S_xS_{1-x})$ stain is developed by neither the coloring ions in $ZrSiO_4$ lattice nor the solid solution of $ZrSiO_4$ and $Cd(S_xS_{1-x})$ but by the small crystals of $Cd(S_xS_{1-x})$ being occluded by the zirconium silicate during sintering process.

Keywords

References

  1. J. Kor. Ceram. Soc. v.23 no.2 A Study on Synthesis of CdS-CdSe Red Stain and Zircon Lee Chong Keun;Kim Chong Ok
  2. J. Amer. Ceram. Soc. v.48 no.5 Color and Structural Character of CdS-CdSe Pigment A. J. Eroles;A. L. Friedberg
  3. Trans. J. Br. Ceram. Soc. v.80 Study of the Mechanism of Formation of a Zircon-Cadmium Sulphoselenide Pigment V. L. Lavilla
  4. Fr. Pat. v.2 no.183 Demande de Brevet D' Invention
  5. Keram. Z. v.30 Zirkonfarbkorper-durch Neuentwick-lungen eine luckenlose Farbpalette fur die Keramische Industrie A. Broll
  6. Keram. Z. v.30 no.688 Einschluβpigmente, Farbkorper nach einem neuen Prinzip D. Kleinchmitt
  7. J. Amer. Ceram. Soc. v.53 no.8 Mechanism of Formation of Zircon Stains R. A. Eppler
  8. Bull. Amer. Ceram. Soc. v.56 Zirconia-Based Colors for Ceramic Glazes R. A. Eppler
  9. Trans. J. Br. Ceram. Soc. v.73 Modern Inorganic Pigments R. W. Batchelor
  10. Trans. Brit. Ceram. Soc. v.61 Preparation and Properties of Some Zirconium Stains F. T. Booth;G. N. Peel
  11. J. Amer. Ceram. Soc. v.53 no.1 Zircon-Vanadium Blue Pigment T. Demiray;D. K. Nath;F. A. Mummel
  12. Compt. Rend. v.261 Vanadium Oxygen System Existence of a New Phase with Composition $VO_{2·33}$ J. Tudo;G. Tridot