Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지

Determination of Water in Magnesium Metaphosphate Glasses

MgO.$P_2O_5$ 유리의 수분 측정

  • 강은태 (경상대학교 재료공학과) ;
  • 박용완 (한양대학교 무기재료공학과)
  • Published : 1986.03.01
Download PDF
⟨ Previous Next ⟩

Abstract

Infrared has been used in determination of water in magnesium metaphosphate glasses. The method consisted of measuring the weight loss and the variation in absorption coefficient at 3, 200$cm^{-1}$. The molar absorptivity of water in magnesium metaphophate glasses was found to 76.9ι$mol^{-1} cm^{-1}$ Using the value for $\varepsilon$, A and Δ$\upsilon$H of the hydroxyl band in the spectra of magnesium metaphosphate. The molar absorptivity of the hydroxyl absorption band at 3, 3130-2, $925cm^{-1}$ in the spectra of MgO.$P_2O_5$ system glasses could be computed. And a variation of molar absorptivity against the MgO/P2O5 ratio has not been shown regulation.

Keywords

References

  1. J. Phys. Chem. Glasses v.3 no.4 Influence of Water Content on the Properties of Vitreous Silica Ⅰ G. Hetherington;K.H. Jack
  2. J.Non-Cryst. Solids v.5 Properties and Structure of Vitreous Silica R. Bruckner
  3. J. Phys. Chem. Glassws v.5 no.3 The Influence of HO and O Atmosphere on the Crystallization of Vitreous Sillica F.E. Wagstaff;S.D. Brown;I.B. Cutler
  4. J. Phys. Chem. Glasses v.3 no.5 The Mechanusm of Electrical Conduction in Lead Silicate Glasses and its Dependence on Water Content G.C. Milnes;J.O. Isard
  5. J. Am. Ceram. Soc. v.52 no.3 Influence of Proton Exchangs on Internal Friction in Alkali Silicate Glasses H. deWaal
  6. Glastech. Ber. v.41 no.2 Contribution to Quantitative Determination of Water Content of Glass from the Infrared OH Bands J. Gotz;E. Vosahlova
  7. Trans. Brit. Ceram. Soc. v.59 Water in Silica Glass G.W. Stepheson;K.H. Jack
  8. Glastech Ber. v.38 Magneische Resonanz in Glasern Werner Muller-Warmuth
  9. Cer. Bulletin v.55 no.5 Direct Determination of Water in Glass J.P. Williams;Y.S. Su;W.R. Strzegowski;B.L. Butler;H.L. Hoover;V.O. Altemose
  10. Nature Infrared Spectra of Silica D.G. Drummond
  11. Glass Ind. v.47 Gases and Water in Glass H. Scholze
  12. Glastech. Ber. v.32 no.3 Incorporation of Water in Glasses 1 H. Scholze
  13. J. Am. Ceram. Soc. v.55 no.1 Determination of Water in Lead Borate Glasses R.J. Eagan;C.G. Bergeron
  14. J. Non-Cryst. Solids v.51 Protonic Conduction in Alkaline Earth Metaphosphate Glasses Containing Water Y. Abe;H. Shimakawa;L.L. Hench
  15. J. Am. Ceram. Soc. v.63 no.11-12 Electrical Condutivity of Na₂O.3SiO₂Glasses with High Water Content M. Takata;M. Tomozawa;E.B. Watson
  16. J. Non-Cryst. Solids v.11 Internal Friction of NaPO Glasses Containing Water D.E. Day;J.M. stevels
  17. J. Mat. Sci. v.14 Determination of the Absorptivity of OH in a Sodium Borosilicate Glass A.D. Pearson;G.A. Pasteur;W.R. Northover
  18. J. Ceram. Assoc. Japan v.76 no.2 Infrared Spectra and some Physical Properties of Divalent Metal Phosphate Glasses Containing Residual Water A. Naruse;Y. Abe;H. Inoue
  19. J. Am. Chem. Soc. v.81 Structure and Properties of Condensed Phosphates E.T. Griffith;C.F. Callis
  20. J. Mat. Sci. v.7 The Effect of Combined Water on the Transfornation Temperature of a Phosphate Glass N.H. Ray;C.J. Lewis
  21. 名工大付屬窯硏報 v.3 Infrared Absorption Spectra of the Residual Water in the Glasses in (TEX)$MOP_2O_5$(/TEX) System A. Naruse;Y. Abe
  22. Z. Elektrochem. v.53 Infrared and Dipole Mesurements on the Interaction Between Solvents and the Hydroxyl Group of Phenol W. Luttke;R. Mecke