Study on Stabilized CdS-CdSe Red Stain A Study on Syntheisis of CdS-CdSe Red Stain and Zircon

안정화 CdS-cdSe계 채료에 관한 연구 제1보 CdS-CdSe 적색채료와 $ZrSiO_4$의 합성

  • 이종근 (한양대학교 공과대학 무기재료공학과) ;
  • 김종옥 (한양대학교 공과대학 무기재료공학과)
  • Published : 1986.02.01

Abstract

Effects of additionof $NH_4Cl$, NaBr and LiF on the formation of Zircon and the synthesis of CdS-Se red stain were investigated by means of XRD, DTA and the color standard and color nomenclature. The red stain of CdS-Se system shows a little difference dependent on firing temperature on firing conditon. Consequently it forms a good soid-solution with red color under the ratio of CdS and Se 3.5 -4.1 at 58$0^{\circ}C$. But it changes to dark red as increasing Se. LiF is the most effective in mineralizer to preparae zircon with the equilbrant molar $SiO_2$ and ZrO Zircon makes a good preparation in 0.33 mole LiF from 90$0^{\circ}C$.

Keywords

References

  1. Coloured Glasses W. A. Wayl
  2. Ceramic Glazes C. G. Harman
  3. J. Soc. Glass Technol. v.16 Color of Selenium Ruby Glasses H. R. Rooksby
  4. J. Amer. Ceram. Soc. v.48 no.5 Color and Structural. Character of CdS-CdSe Pigment A. J. Eroles;A. LFriedberg
  5. Glashutte v.64 no.22 Cadmium Red Enamels L. Stuckert
  6. J. Kor. Ceram. Soc. v.9 no.1 A Study on CdS-Se Stain Chong Keun Lee;C. Y. Kim
  7. J. Amer. Ceram. Soc. v.16 Selenium Ruby Glass. Preparation and X-ray Study M. H. Bigelow;Silverman Alexander
  8. U. S. Pat. 2, 134, 055 Method of Making Cadmiun Red W. F. Meister;N. J. Elizabeth
  9. U. S. Pat. 2, 176, 495 Method of Producing Cadmium Selenids N. E Gordon;E. C Pitzer
  10. U. S. Pat. 2, 523, 119 Pigment and Method of Producing Same D. O Kenworthy
  11. U. S. Pat. 2, 441, 407 Ceramic Pigment C. A. Seabright
  12. Trans. Brit. Ceram. Soc. v.61 Preparation and Properties of Same Zirconium Stains F.T. Booth;G.N Peel
  13. J. Amer. Ceram. Soc. v.53 no.8 Mechanism of Formation of Zircon Stains R. A. Eppler
  14. Trans. J. Br. Ceram. Soc. v.80 Study of the Mechanism of Formation of a Zircon-Cadmium Sulphoselenide Pigment V.L Lavilla
  15. Color Standard and Color Nomenclature R. Robert
  16. Kogyo Kayaku Zasshi Effects of NH₄CO₃ and NaF of the Formation of Zircon Tazio Hibino;Toshiyi Yamazaki;Hitoshi Sekiya
  17. 日本工業化學雜誌 v.70 no.3 ジルコソ合成(におよぽす)低融点 不純物の影響 日比野 泰三;三浦英二;閑谷
  18. J. Jap. Ceram. Soc. v.88 no.10 Effects of Addition of Sodium Fluoride and Manganese Oxide in Combination of the Formation of Zircon E. Miura;R. Furumi;M. Hashiba;Y. Nurish;T. Hibino