첨가재에 의한 저밀도 폴리에틸렌의 내트리잉성 향상

Improvement of the resistance to Treeing by additive in Low Density Polyethylene

Discussions on this paper are related to the effects of organic materials to treeing phenomena of low density polyethylene. As additives, 11 kinds of organic compounds are selected by considering the respective features such as melting point, boiling point, electron affinity as well as molecular structure, and then the specimens of low density polyethylene are prepared by blending with 10wt% of the selected additives. For the comparison of effectiveness of treeing resistance and interpretation of the mechanism of compounds as treeing retardants, several investigations such as the tree acceleration test, the prestressed test and the measurement of internally occurred partial discharge are carried out. As the results, meta-Cresol is regard as the most effective retardant among those, and it is supposed that this aromatic compound to be comprised of radical having large electron affinity has strong capability to accept energetic electron to prevent or delay the growth of discharge streamer. Furthermore, by activating partial discharge at the wall of tree pit through the function of trapped electron at this material, the gas pressure in the pit is increased up to prevent the growth of streamer.