Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Synthesis and Characterization of Substituted Quinoline Complexes of Molybdenum (I). Substituted Quinolinium Salts of Pentachlorooxomolybdate (V)

몰리브덴(V)의 퀴놀린계 착물합성과 그 성질 (제2보). 오클로로옥소몰리브덴(V) 산의 치환퀴놀린윰염

  • Kwang Lee (Department of Chemistry, Keimyung University) ;
  • Sang-Oh Oh (Department of Chemistry, Kyungpook National University)
  • 이광 (계명대학교 자연과학대학 화학과) ;
  • 오상오 (경북대학교 자연과학대학 화학과)
  • Published : 1985.10.20
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Abstract

The substituted quinolinium salts of pentachlorooxomolybdate (V) have been synthesized and characterized by means of the investigation of elemental analysis, infrared spectra, electron spectra, electric conductivity. The results of elemental analysis were well coincided with the theoretical value and all prepared salts were mononuclear complexes. The complexes were binary univalent electrolytes and analyzed d-d transition and charge transfer transition.

오클로로옥소몰리브덴(V)산의 치환퀴놀린윰염을 합성하고 착물의 원소분석, 적외선흡수 스펙트럼, 전자스펙트럼, 전기전도도를 측정하였다. 착물은 2:1전해질이고 치환퀴놀린류는 양이온 상태로 존재하고 있으며 착물의 음이온은 단위체이다. 착물의 결정장전이와 전하이동전이를 해석하였다.

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References

  1. Ber. v.34 B. Klason
  2. J. Chem. Soc. R.G. James;Wardlaw
  3. J. Chem. Soc. Henry Mills Spittle;William Wardlaw
  4. Inorg. Chem. v.3 E.A. Allen;M.F. Neuman
  5. J. Chem. Soc. E.A. Allen;B.J. Bridson;D.A. Edward;G.W.A. Fowles;R.G. Wiliams
  6. J. Chem. Soc. (A) B.J. Bridson;D. A. Edwards;D.J. Machin;K.S. Murry;R.A. Walton
  7. J. Chem. Soc. J.H. Garside
  8. J. Chem. Soc. D. Brown
  9. J. Indian. Chem. Soc. v.44 M.C. Halder;H.K. Saha
  10. Inorg. Chimica. Acta. v.7 H. Sabat;M. F. Rudolf;B. Jezowska-Trebiatowska
  11. J. Indian Chem. Soc. v.44 R. L. Dutta;B. Chatterjee
  12. Inorg. Chem. v.1 C.J. Ballhausen;H.B. Gray
  13. Inorg. Chem. v.1 H.B. Gray;C.R. Hare
  14. Inorg. Chem. v.1 C.R. Hare;I. Bernal;H.B. Gray
  15. Methods of Quantitative Inorganic Analysis K. Kodama
  16. J. Am. Chem. Soc. v.71 H. Freiser;W. L. Glowacki
  17. J. Am. Chem. Soc. v.71 R. B. Hanna. Jr;J.H. Lieblich;A. G. Renrew
  18. The Infrared Spectra of Complex Molecules J.L. Bellamy
  19. Chem. Pharm. Bull. v.4 Hideyo Shindo;Shinzo Tamura
  20. Chem. Pharm. Bull. v.8 Hideyo Shindo
  21. J. Am. Chem. Soc. v.81 Clarence Karr, Jr.;Patricia A. Estep;Anthony J. Papa
  22. J. Chem. Soc. R.G. James;W. Wardlaw
  23. Z. Anorg. Allg. Chem. v.318 Von H. Funk;H. Bohland
  24. 大韓化學會誌 v.7 崔圭源;吳浚錫;李光雨
  25. Textbook of Quantitative Inorganic Analysis Vogel. Arthur I
  26. J. Am. Chem. Soc. v.54 R.C. Young
  27. Infrared Spectroscopy Margareta Avram
  28. The Aldrich Library of Infrared Spectra C.J. Pouchert
  29. 대한화학회지 v.25 吳相午;金昌洙
  30. J. Mo. Struct. v.19 B. Jezowska-Trzebiatowska;J. Hanuza
  31. Inorg. Chem. v.5 Sabatini;Bertini
  32. J. Inorg. Nucl. Chem. v.34 H.K. Saha;M.C. Halder
  33. J. Inorg. Nucl. Chem. v.33 H.K. Saha;M.C. Halder
  34. 대한화학회지 v.6 金昌洙;吳相午
  35. Austr. J. Chem. v.12 G. J. Sutton