Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Amination of Organic Azides using Tetracarbonylhydridoferrate(O) as a Reducing Agent(I)

환원시약인 테트라카르보닐철산염(O)을 이용한 유기아지드화물의 아미노화 (제1보)

  • Sang Chul Shim (Department of Industrial Chemistry, Kyungpook National University) ;
  • Kui Nam Choi (Department of Industrial Chemistry, Kyungpook National University)
  • 심상철 (경북대학교 공과대학 공업화학과) ;
  • 최귀남 (경북대학교 공과대학 공업화학과)
  • Published : 1985.08.20
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Abstract

Organic azides were reduced to organic amines in the presence of tetracarbonylhydridoferrate(O) as a highly selective reducing agent at room temperature under carbon monoxide atmosphere. Particularly, benzoylazide gave ethylphenylcarbamate at room temperature but gave benzamide quantitatively at -40$^{\circ}$ in the presence of tetracarbonylhydridoferrate under carbon monoxide atmosphere.

유기아지드화물은 일산화탄소대기압하, 실온에서 높은 선택적 환원시약인 테트라카르 보닐철산염의 존재하에서 높은 수득율의 아민으로 환원되었다. 특히 벤조일아지드는 동일시약내 일산화탄소 대기압 실온에서는 에틸페닐카바메이트를 주나, -40$^{\circ}$에서는 정량적으로 벤즈아미드가 얻어졌다.

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