Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Synthesis of 1-[3-(Propylthio)butyryl]-2,6,6-trimethylcyclohexene

1-[3-(프로필티오) 부티릴]-2,6,6-트리메틸시클로헥센의 합성

  • Jong Hoon Oh (Department of Chemistry, Seoul National University) ;
  • Kyong Tae Kim (Department of Chemistry, Seoul National University) ;
  • Yong Tae Kim (Korea Ginseng and Tobacco Research Institute)
  • 오종훈 (서울대학교 자연과학대학 화학과) ;
  • 김경태 (서울대학교 자연과학대학 화학과) ;
  • 김용태 (한국인삼연초연구소)
  • Published : 1985.06.20
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Abstract

1-[3-(Propylthio)butyryl]-2,6,6-trimethylcyclohexene (18) was synthesized from the reaction of 2,6,6-trimethylcyclohex-l-en-1-yllithium (9) with 3-propylthiobutyraldehyde (16). This method will be employed to prepare 1-[3-(methylthio)butyryl]-2,6,6-trimethylcyclohexene (1) which is known as one of the powerful flavors and fragrances.

2,6,6-trimethylcyclohex-l-en-1-yllithium (9)과 3-propylthiobutyraldehyde (16)의 반응으로 부터 1-[3-(Propylthio)butyryl]-2,6,6-trimethylcyclohexene (18)을 합성하였다. 이 방법을 이용하여 강력한 향료로 알려진 1-[3-(methylthio)butyryl]-2,6,6-trimethylcyclohexene (1)을 합성할 것이다.

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References

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