Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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$^{13}$C NMR Study of Segmental Motions of n-Heptane in Neat Liquid

  • Min, Buem-Chan (Department of Chemistry, Seoul National University) ;
  • Chang, Sei-Hun (Department of Chemistry, Seoul National University) ;
  • Shin, Kook-Joe (Department of Chemistry, Seoul National University) ;
  • Lee, Jo-Woong (Department of Chemistry, Seoul National University)
  • Published : 1985.12.20
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Abstract

Carbon-13 nuclear spin-lattice relaxation times have been measured over the range of temperature from 213K to 353K for carbons in n-heptane in neat liquid. The experimental data have been analyzed to obtain informations of segmental motions in the chain polymers by employing a model which describes jumps between several discrete states with different lifetimes. The overall reorientation of the molecule is assumed to be isotropic rotational diffusion. From the above analysis the activation energies of each C-C bond reorientation as well as the overall reorientation have been obtained through the Arrhenius-type temperature dependence.

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