Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Kinetics of the Photochemically Generated t-Butoxy Radical Reactions with Phosphine(PH$_3)^*$

  • Published : 1985.08.20
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Abstract

The gas phase reactions of the photochemically generated t-butoxy radicals with phosphine ($PH_3$) were studied in the temperature range of $35-80^{\circ}C.$ We found the significant differences between high temperature thermal reactions and low temperature photo reactions. In comparison with the reactions of t-butoxy radicals with other hydrogen donors, some possible mechanistic suggestions were made for the explanation of the results.

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References

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