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Theoretical Estimation of Partial Miscibilities by the Extended Flory-Huggins Lattice Theory

  • Jung, Hae-Young (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Jhon, Mu-Shik (Department of Chemistry, Korea Advanced Institute of Science and Technology)
  • 발행 : 1985.06.20

초록

Four types of the phase diagrams indicating the partial miscibilities in polymer-polymer or polymer-solvent systems have been explained in terms of the extended Flory-Huggins lattice theory. In this article, the term $kT_{\chi}$ in the theory is expressed as a function of temperature. Using such $a_{\chi}$-parameter, the simplest forms of geometrical conditions are derived for each type of the four partial miscibilities in polymer systems. The calculated partial miscibilities are in good agreement with the experiment.

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참고문헌

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