Bulletin of the Korean Chemical Society

  • 제6권3호
  • /
  • Pages.124-127
  • /
  • 1985
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Kinetic Study on Bromine-Exchange Reaction of Antimony Tribromide with $\alpha$-Phenylethyl Bromide in Nitrobenzene

  • 발행 : 1985.06.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

The kinetic study on the bromine-exchange reaction of antimony tribromide with ${\alpha}$-phenylethyl bromide in nitrobenzene has been carried out, using Br-82 labelled antimony tribromide. The results show that the exchange reaction is first order with respect to ${\alpha}$-phenylethyl bromide, and either second or first order with respect to antimony tribromide depending on its concentration. It is also concluded that ${\alpha}$-phenylethyl bromide exchanges bromine atom with antimony tribromide much faster than other organic bromides previously examined. Reaction mechanisms for the exchange reaction are discussed.

키워드

참고문헌

  1. J. Amer. Chem. Soc. v.87 Sang Up Choi;J. E. Willard
  2. J. Phys. Chem. v.72 Oh Chun Kwun;Sang Up Choi
  3. J. Korean Chem. Soc. v.14 Sang Up Choi
  4. J. Korean Chem. Soc. v.20 Oh Chun Kwun;Sang Up Choi
  5. Bull. Korean Chem. Soc. v.2 Oh Chun Kwun;Young Cheul Kim;Sang Up Choi
  6. Bull. Korean Chem. Soc. v.2 Oh Chun Kwun;Young Cheul Kim;Sang Up Choi
  7. Bull. Korean Chem. Soc. v.3 Sang Up Choi;Young Il Pae;Sok Hwan Rhyu
  8. Bull. Korean Chem. Soc. v.5 Sang Up Choi;Sok Hwan Rhyu
  9. Nuclear and Radiochemistry G. Friedlander;J.W. Kennedy;E.S. Macias;J. M. Miller
  10. J. National Acad. Sciences, Republic of Korea, Natural Sciences Series v.23 Sang Up Choi;Sok Hwan Rhyu