Bulletin of the Korean Chemical Society

  • 제6권2호
  • /
  • Pages.95-98
  • /
  • 1985
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Photocycloaddition Reaction of trans-Cinnamonitrile Derivatives with Tetramethylethylene

  • Chae, Myeong-Yun (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Yoon, Suk-Kyoon (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Shim, Sang-Chul (Department of Chemistry, Korea Advanced Institue of Science and Technology)
  • 발행 : 1985.04.20
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초록

Stereospecific [2 + 2] cycloadducts are obtained as major products when trans-cinnamonitrile derivatives are irradiated with excess tetramethylethylene. The fluorescence quenching studies, weak exciplex fluorescence, and sensitization by benzophenone suggest that this stereospecific photochemical cycloaddition reaction involves singlet exciplex intermediate formed between cinnamonitrile derivatives and tetramethylethylene.

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참고문헌

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피인용 문헌

  1. A practical liquid crystal mixture for IR applications vol.30, pp.5, 1985, https://doi.org/10.1080/0267829031000107716