Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지

Synthesis of Vinyl Derivative of Cyclic Triphosphazene and Its Graft Copolymerization on Collulose

Cyclic Triphosphazene의 Vinyl 유도체의 합성과 셀룰로오스에의 그라프트 중합반응

  • 표희수 (연세대학교 이과대학 화학과) ;
  • 채희주 (연세대학교 이과대학 화학과, 연세대학교 이과대학 화학과, 서울대학교 공과대학 섬유공학과)
  • Published : 1985.04.01

⟨ Previous Next ⟩

Abstract

Penta (2, 3-dibromopropoxy) allyloxycyclotriphosphazene, N3P3OCH2CH=CH2(OCH2CHBrCH2Br)5 was synthesized and identified by IR, mass spectroscopy and elemental analysis of C,H,N and halogen. This vinyl monomer could be grafted on cellulose by CeIV initiation without opening its aromatic phosphazene ring. After extraction of homopolymer, thermal behavior of grafted cellulose was studied and compared with that of pure cellulose by TGA and DSC analysis. Grafted cellulose showed two typical double peaks at 240 and 274$^{\circ}C$ in DSC curve, lowered the decomposition temperature, and increased the amount of char. It suggested that decomposition mechanism of grafted cellulose is different from that of pure cellulose, which leads to improvement in flame retardant property.

Keywords