A Study of Carbon Monoxide Oxidation on Pt & Pt-Pd Catalysts

귀금속촉매 (Pt, Pd)를 이용한 일산화탄소 산화반응에 관한 연구

  • 金京林 ;
  • ;
  • ;
  • 이원묵 (연세대학교 화학공학과) ;
  • 유홍진 (연세대학교 화학공학과)
  • Published : 1985.11.01

Abstract

This study is concerned with the oxidation of carbon monoxide on platinum and platinum-palladium catalysts. Catalysts were made by the impregnation method and flow reactor was used in the catalytic reaction. As for the mixed gases, carbon monoxide concentration varied from 1 to 4% and that of oxygen from 1 to 4%. $N_2$ was used as carrier gas and GHSV varied from 24, 000 $h^{-1} to 60, h^{-1}$. The temperature range was from 200 to $600^\circ$C. It was also taken into consideration that the heat and mass transfer resistance of our catalysts was negligible in the study. Experimental results showed that platinum-palladium catalyst was about 1.5-3.9% superior to platinum catalyst in conversion yield. When we used platinum-palladium catalyst, we observed that carbon monoxide oxidation was found to be 1 st order with respect to carbon monoxide concentration. Activation energy of the catalyst was 23.5 kcal/mol.

Keywords

References

  1. J. Catal v.54 Noel,W.Cant,;P.C.Hicks;B.SLennon
  2. Catal. Rev. v.6 Francis G. Dwyer
  3. J. Catal. v.51 Jack C. Summers;L. Louis Hegedus
  4. Mass Transfer in Heterogeneous Catalysis Charles,N.Satterfield
  5. Ind. Eng. Chem. Prod. Res. Develop. v.12 Stering E.Voltz;Charles;R.Morgan,David Liedermann;Solomon,M.Jacob
  6. J. Catal v.44 F.M.Hoffmann;A.M.Bradshow
  7. B.T.L. v.63 S.J.Stephens
  8. The Chemisorptive bond basic concept A.Clark
  9. 수증기하에서 일산화탄소의 copper chromite 촉매에 의한 산화반응 W.K.Lee
  10. Adv. in Catal. v.24 James Wei
  11. J. Catal. v.65 Richard K. Herz;Samuel P. Martin.
  12. J. Catal. v.46 K.F.Blurton;J.R.Stetter
  13. J. Catal. v.36 John S.Close;John M.White
  14. Chemical ReactionEngineering Octave Levenspiel
  15. J. Catal. v.36 A.Palazove;C.C.Chang;R.J.Kokes
  16. J. Catal v.64 Tatsuto Matsushima
  17. J. Chem. Phys. v.69 Engel,T.;Ertl,G.
  18. v.39 E.McCarthy;J.Zahradnik;G.C.Kuczyyski;J.J.Carberry
  19. J. Catal. v.55 Tatsuo Matsushima
  20. J. Catal. v.64 Charles,M.Grill;Ricard D.Gonzales
  21. SAE Print No. 710290, SAE Automotive Engineering Congress HC/CO Oxidation Catalysts for Vehicle Exhaust Emission Control K.I.Jagel;F.G.Dwyer
  22. J. Catal. v.59 H.C.Yao;M.Sig;H.K.Plummer.Jr.
  23. J. Catal. v.50 S.Yamaguchi
  24. J. Catal. v.59 S.H.Oh;K.Baron;E.M.Sloan;L.L.Hebedus
  25. Adsorption-Desorption Phenomena Ertl,G.;Koch,J.;F.Rica(ed.)
  26. J. Chem. Phy. v.69 Engel,T.;Ertl,G.
  27. Yonsei Eng.Report v.14 no.1 김경림