Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Study of Molecular Reorientation in Liquid with Raman Spectroscopy. Intermolecular Interaction of Hexafluorobenzene with Benzene

  • Hwang, Hyun-Jin (Department of Chemistry, Seuol National University) ;
  • Kim, Kwan (Department of Chemistry, Seoul National University) ;
  • Kim, Myung-Soo (Department of Chemistry, Seoul National University)
  • Published : 1984.12.20
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Abstract

Raman spectroscopy was used to study the reorientational motion of hexafluorobenzene in benzene and also in neutral solvents. From the viscosity dependence of the reorientation time, intermolecular interaction in the systems was investigated. No evidence was found to support the presence of long-lived 1:1 complex of hexafluorobenzene and benzene. The unusual viscosity dependence of the reorientational motion observed in the systems was explained as due to the formation of transient complexes.

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