$BaTiO_3-SrTiO_3$ 계의 유전성

Dielectric Properties of $BaTiO_3-SrTiO_3$ System

  • 윤기현 (연세대학교 요업공학과) ;
  • 이남양 (연세대학교 요업공학과) ;
  • 조경화 (연세대학교 요업공학과)
  • 발행 : 1984.04.01

초록

$BaTiO_3$ and $SrTiO_3$ were mixed with the mole ratio of 35:65, 50:50 and 65:35 and heated at 1100~120$0^{\circ}C$ for 1~64 hours. The dielectrics of $BaTiO_3$-$SrTiO_3$ system were investigated as a function of amount of solid solution formed. The dielectric constant was increased and Curie temperature was shifted to higher temperature with increasing of heating of soaking time for the same composition and heating temperature. This can be explained by the homogeneous distribution of $Ba^{2+}$ and $Sr^{2+}$ ion in the $BaTiO_3$ system. The Curie temperature was shifted to lower temperature with increasing $SrTiO_3$ in the $BaTiO_3$-$SrTiO_3$system because of decreasing the lattice constant.

키워드

참고문헌

  1. J. Am. Ceram. Soc v.38 no.12 Structural Bchavior in the System(Ba,Ca,Sr)TiO₂and Its Relation to Certain Dielectric Characteristics Malcolm McQuarrie
  2. J. Am. Ceram. Soc. v.30 no.4 Properties of Barium-Strontium Titanate Dielectrics E.N. Bunting;G.R. Shclton;A.S. Creamer
  3. Phys. Rev v.124 no.5 Dilectric and X-ray Study of $CaхBa_1-xTiO₃and Ca_\Sr_1-xTiO₃$ T. Misui;W.B. Westphal
  4. J. Appl. Phys. v.47 no.1 Grainsize Effect on Dielectric Properties in Barium Tianate Ceramics Kyoichi Kinoshita;Akihiko Yamaji
  5. Phys. Rev v.125 no.6 Microwave Losses in Strontium Titanate above the Phasc Transition G. Rupprecbt;R.O. Bell
  6. J. Appl. Phys v.46 no.1 Anomalous Capacitance of Schottly Barriers on Strontium Titanate R.C. Nevile;B. Hoeneisen
  7. J. Phys. Chem. Solids v.11 Dielectric Properties of Single Crystals of SrTiO₃ H.E. Weaver
  8. Introduction to Ceramics W.D. Kingery;H.K. Bowen;D.R. Uhimann
  9. J. Am. Ceram. Soc. v.40 no.11 Phase Equilibria in the System BaTiO₃ J.A. Basmajian;R.C. DeVries
  10. J. Am. Ceram. Soc v.33 no.4 Solid Solubility of Barium,Strontium and Calcium Titanates G. Durst;M. Grotenguis;A.G. Barkow
  11. J. Phys. Soc. Jpn v.11 no.9 Solid State Relation between Barium Titanate and Strontium Titanate Shoichiro Nomura
  12. J. Am. Ceram. Soc v.35 no.12 Lattice Constants and Dielectric Properties of Barium Titanate-Barium Stannate-Strontium Titanate Bodies R.H. Dungan;D.F. Kane;L.R. Bickford
  13. Phys. Rev v.77 no.7 The Effect of Hydrostatic Pressure on the Curie Point of Barium Titanate Single Crystals W.J. Merz
  14. J. Am. Ceram. Soc v.42 no.6 The Systems BaO-SrO-TiO₂,BaO-CaO-TiO₂and SrO-CaO-TiO₂ W. Kwestroo;H.A.M. Paping
  15. Phys. Rev v.78 Lorentz Correction in Barium Tianale J.C. Slator