Persistence of 2,4-D and MCPP in Soil

토양중(土壤中) 2,4-D와 MCPP의 잔류특성(殘留特性)

A study was undertaken to investigate the persistence of 2,4-D and MCPP in two different Suweon soils under field conditions. MCPP was extracted from soil with aqueous calcium hydroxide solution and then derivatized to pentafluorobenzyl ester to enhance the electron capture sensitivity. Total recovery of MCPP from soil was 85.6% and the detection limit for 20g sample was 0.02 ppm. Ethyl ester of 2,4-D applied to soil was rapidly hydrolysed to 2,4-D with the half-life of less than 1 day. Half-life of total 2,4-D ethyl ester, including 2,4-D, incorporated into soils at a rate of 0.045 ㎏ a.i./10a was $4{\sim}7$ days and that of under laboratory conditions was $7{\sim}8$ days. Half-life of MCPP applied at a rate of 0.25㎏ a.i./10a under field conditions was $9{\sim}12$ days and that of under laboratory conditions was $12{\sim}23$ days.

수원소재(水原所在) 2개토양(個土壤)에서 2,4-D ethyl ester 및 MCPP의 토양중(土壤中) 잔유소장(殘油消長)을 조사(調査)한 결과(結果)는 다음과 같다. 1) 살포(撒布)한 2,4-D ethyl ester는 토양중(土壤中)에서 신속(迅速)히 가수분해(加水分解)되어 2,4-D를 생성(生成)하였다. 2) 포장조건하(圃場條件下)에서 2,4-D 잔유분(殘留分)을 포함한 총(總) 2,4-D ethyl ester의 반감기(半減期)는 $4{\sim}7$일(日)이었으며 실험실(實驗室) 조건하(條件下)에서는 다소 긴 $4{\sim}7$일(日)이었다. 3) 포장조건하(圃場條件下)에서의 토양중(土壤中) MCPP의 반감기(半減期)는 $9{\sim}12$일(日)이었고 실험실(實驗室) 조건하(條件下)에서는 다소 긴 $12{\sim}23$일(日)의 반감기(半減期)를 보였다.