Bulletin of the Korean Chemical Society

  • 제4권5호
  • /
  • Pages.197-200
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  • 1983
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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MO Theoretical Studies on Diels-Alder Reactions of $\alpha$-Allenic Ketones$^*$

  • 발행 : 1983.10.20
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초록

The Diels-Alder cycloaddition reactions between dienes and allenic ketones were studied theoretically using CNDO/2 method. It was found that the reaction is a neutral electron demand type with matrix element control and the reactivity, the regio- and stereo-selectivities can be correctly predicted based on interaction energies calculated with the 4-center FMO formalism.

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참고문헌

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피인용 문헌

  1. Intramolecular Diels-Alder Reaction with Furan-Diene. Activated Allene as Dienophile in a BCD-ring Approach to Steroids vol.96, pp.2, 1983, https://doi.org/10.1002/bscb.19870960205