Bulletin of the Korean Chemical Society

  • 제4권2호
  • /
  • Pages.95-99
  • /
  • 1983
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Photoreaction of 8-Methoxypsoralen with Thymine

  • Shim, Sang-Chul (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Kim, Yong-Zu (Department of Chemistry, Korea Advanced Institute of Science and Technology)
  • 발행 : 1983.04.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Photoreaction of 8-methoxypsoralen (8-MOP) with thymine (${\ge}$ 300 nm) was carried out in the dioxane-water frozen state. One major and two minor monoaddition products between 8-MOP and thymine were isolated by various chromatographic methods. Major monoadduct was characterized to be a C4 cycloaddition product formed between 5,6-double bond of thymine and 3,4-double bond of 8-MOP with cis-anti stereochemistry. Two minor adducts were proved to be stereoisomers of this major adduct.

키워드

참고문헌

  1. Sunlight and Man M. A. Pathak(ed.);L. C. Harber(ed.);M. Seiji(ed.);A. Kukita(ed.)
  2. Chem. Soc. (Chem. Commun.) J. E. Land;F. A. P. Rushton;R. L. Beddoes;J. M. Bruce;R. J. Cernik;S. C. Dawson;O. S. Mills
  3. Photochem. Photobiol. v.29 P-S. Song;J. K. Tapley
  4. Photochem. Photobiol. v.6 L. Musajo;F. Bordin;R. Bevilacqua
  5. Photochem. Photobiol. v.6 L. Musajo;F. Bordin;G. Caporale;S. Marciani;G. Rigatti
  6. Photobiochem. Photobiophys. v.3 B. S. Hahn;P. C. Joshi;L. S. Kan;S. Y. Wang
  7. Photochem. Photobiol. v.30 S. C. Shim;K. H. Chae
  8. Photochem. Photobiol. v.30 S. C. Shim;H. Y. Koh;D. Y. Chi
  9. Chem. Lett. v.11 S. C. Shim;D. Y. Chi
  10. Z. Naturforsch. v.31 F. Baccichetti;F. Bordin;S. Marciani;F. Dall'Acqua;G. Rodighiero
  11. Photophysiology v.VII L. Musajo;G. Rodighiero;C. Giese(ed.)
  12. Photochem. Photobiol. v.29 F. Dall'Acqua;S. M. Mango;F. Zambon;G. Rodighiero
  13. Z. Naturforsch. v.29c F. Dall'Acqua;S. Marciani;D. Vedaldi;G. Rodighiero
  14. Biochim. Biophys. Acta. v.254 R. S. Cole
  15. J. Bacteriol. v.107 R. S. Cole
  16. Photochem. Photobiol. v.24 M. L. Harter;I. C. Felkner;P.-S. Song
  17. J. Amer. Chem. Soc. v.103 K. Straub;D. Kanne;J. E. Hearst;H. Rapoport
  18. Biochemistry v.21 D. Kanne;K. Straub;H. Rapoprt;J. E. Hearst