저장중(貯藏中) 참깨의 결합형태별(結合形態別) 지질(脂質)의 지방산(脂肪酸) 조성변화(組成變化)

Changes in Fatty Acid Compositions of Sesame Seed Lipid Fractions during Storage

steryl ester구성지방산(構成脂肪酸)으로서 plamitic acid와 stearic acid는 모든 저장조건(貯藏條件)에서 감소(減少)하였고 linoleic acid는 증가(增加)하였다. 또한 $C_{18}$/$C_{16}$지방산비(脂肪酸比)는 통기저장(通氣貯藏)이 밀봉저장(密封貯藏)보다 전(全) 저장기간(貯藏期間)에서 높았다. triglyceride의 구성지방산(構成脂肪酸)으로서 palmitic acid와 stearic acid는 모든 저장조건(貯藏條件)에서 저장(貯藏) 9개월(個月)까지는 감소(減少)하였다가 9개월(個月) 이후(以後)에는 증가(增加)하였다. oleic acid와 linoleic acid는 저장(貯藏) 9개월(個月)까지는 증가(增加)하였다가 그 이후(以後)에는 다시 감소(減少)하였다. 또한 $C_{18}$/$C_{16}$지방산비(脂肪酸比)와 불포화도비(不飽和度比)는 통기저장(通氣貯藏) 밀봉저장(密封貯藏)보다 높은 경향(傾向)이었다. free fatty acid 구성지방산(構成脂肪酸)으로서 palmitic acid와 stearic acid는 저장(貯藏) 9개월(個月)까지는 감소(減少)하였다가 그 이후(以後)부터는 증가(增加))하였다. 그러나 oleci acid와 linoleic acid는 저장(貯藏) 9개월(個月)까지는 감소(減少)하였다가 그 이후(以後)부터는 다시증가(增加))하였다. 한편 불포화도비(不飽和度比)는 통기저장(通氣貯藏)이 밀봉저장(密封貯藏)보다 높았다.

The changes in fatty acid compositions of the each fraction of oil, that is, steryl ester, triglyceride, diglyceride and free fatty acid, were analyzed during the storage of sesame seed for 4, 9, and 15 months at four different storage conditions, that is, storage under light with linen pouch(LA), storage in dark with linen pouch(DA), storage under light with poly ethylene pouch(LS), and storage in dark with poly ethylene pouch(DS). In the fatty acid composition of steryl ester fraction, palmitic and stearic acid were decreased but linoleic acid was increased during the storage in all the storage conditions. The ratio of $C_{18}$ to $C_{16}$ fatty acids in steryl ester from DA and LA was higher than that from DS and LS during storage until 15 months. The palmitic and stearic acid content in triglyceride were decreased until 9 months of storage, then slightly increased until 15 months of storage in all the storage conditions, but reverse tendency was observed in the lineoleic acid content. The ratio of $C_{18}$ to $C_{16}$ fatty acids and unstaturated to saturated fatty acids in DS were slightly higher than these in DA and LA. In the fatty acid composition of free fatty acid, the content of palmitic and stearic acid were decreased until 9 months of storage, then increased until 15 months, but reverse tendency was observed in the oleic and linoleic acid: the ratio of unsaturated to staturated fatty acids in DA and LA was higher than that in DS and LS during the storage for 15 months.