Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
권호 표지

Synthesis and Characterization of Substituted Pyridine Complexes of Molybdenum (Ⅳ). Oxotrichlorobis(substituted pyridine) molybdenum (Ⅴ)

몰리브덴의 피리딘계 착물합성과 그 성질 (제4보) 옥소삼클로로비스(치환피리딘)몰리브덴 (V)

  • Chang Su Kim (Department of Chemistry, College of Education, Daegu University) ;
  • Sang Oh Oh (Department of Chemistry, Kyungpook National University)
  • 김창수 (대구대학교 사범대학 화학과) ;
  • 오상오 (경북대학교 자연과학대학 화학과)
  • Published : 1982.12.30
Download PDF
⟨ Previous Next ⟩

Abstract

Green crystalline salts of substituted pyridinium oxopentachloromolybdates(V) were obtained from concentrated hydrochloric acid solution of molybdenum(V)-thiocyanate extract. $MoOCl_3(X-py)_2$ (X-py were 4-and 3-cyanopyridine, 2-amino-4-picoline and 4-acetylpyridine) were obtained by reflux of the corresponding substituted pyridinium salts of oxopentachloromolybdates(Ⅴ) in absolute ethanol. ($X-pyH_2$)[$MoOCl_5$]$H_2$O containing the $MoO^{3+}$ group are dissolved and hydrolysed in water but $MoOCl_3(X-py)_2$ are insoluble in water, alcohol and acetone. The complexes are paramagnetic compounds.

옥소클로로몰리브덴(Ⅴ)산 치환피리딘늄의 초록색결정은 몰리브덴(V)-티오시안산 추출용액의 진한 염산용액에서 얻었다. $MoOCl_3(X-py)_2$(X-py는 4-시아노피리딘, 3-시아노피리딘, 2-아미노-4-피코린 및 4-아세틸피리딘)은 무수알코올에서 ($X-pyH_2$)[$MoOCl_5$]$H_2$O을 환류시켜 염화수소를 날려보낸 다음 얻었다. $MoO^{3+}$를 가지는 (X-pyH)$_2$[MoOCl]$_5$$H_2$O는 물에 용해되어 가수분해되나 MoOCl$_3$(X-py)$_2$는 알코올 및 아세톤등에 녹지 않았다. (X-pyH)$_2$[MoOCl]$_5$$H_2$O는 상자성의 전해질이나 MoOCl$_3$(X-py)$_2$는 상자성의 비전해질 착물임을 알았다.

Keywords

References

  1. J. Kor. Chem. Soc. v.25 Sang Oh Oh;C. S. Kim
  2. J. Kor. Chem. Soc. v.25 Sang Oh Oh;C. S. Kim
  3. J. Kor. Chem. Soc. v.26 Sang Oh Oh;C. S. Kim
  4. J. Inorg. Nucl. Chem. v.25 P. C. H. Mitchell
  5. J. Inorg. Nucl. Chem. v.33 H. K. Saha;M. C. Halder
  6. J. Inorg. Nucl. Chem. v.34 H. K. Saha;M. C. Halder
  7. Inorg. Chem. v.4 K. Feeman;G. W. A. Fowles
  8. J. Inorg. Nucl. Chem. v.27 D. A. Edwards
  9. Inorg. Chem. v.1 S. M. Horner;S. Y. Tyree, Jr.
  10. Inorg. Chem. v.5 M. L. Larson;F. W. Moore
  11. J. Amer. Chem. Soc. v.83 D. J. Phillips;S. Y. Tyree JR.
  12. Textbook of quantitative inorganic analysis(4th Ed.) A. I. Vogel
  13. J. Chem. Soc. R. G. James;W. Wardlaw
  14. Electrochemical methods A. J. Bard;L. R. Faulkner
  15. J. Inorg. Nucl. Chem. v.24 G. P. Haight, Jr.
  16. Bull. Soc. Chim., France. v.23 J. P. Simon;P. Souchay
  17. Austral. J. Chem. v.15 G. J. Sutton
  18. Nature v.219 A. Kay;P. C. H. Mitchell
  19. J. Chem. Soc. (A) R. N. Jowitt;P. C. H. Mitchell
  20. J. Chem. Soc. C. G. Barraclough J. Lewis;R. S. Nyholm
  21. Inorg. Chem. v.13 N. E. Netwon;J. L. Corbin;D. C. Bravard;J. E. Searles;J. W. McDonald
  22. Inorg. Chem. v.4 F. Fara;R. T. Iwamoto
  23. J. Inorg. Nucl. Chem. v.28 R. A. Walton
  24. J. Chem. Educ. v.51 L. C. Nathan
  25. Inorg. Chem. v.1 C. J. Ballhausen;H. B. Gray
  26. Ionrg. Chem. v.1 H. B. Gray;C. R. Hare
  27. Inorg. Chem. v.2 S. M. Horner;S. Y. Tyree, JR.