The Fluorescence Study on the Chlorophyll Complexes of Silicon-Pyridine Polymers (III)

Chlorophyll과 Silicon-Pyridine 중합체의 착물에 대한 형광연구 (제3보)

  • Uoo-Tae Chung (Pharmaceutical Department of Chung-Puk National University) ;
  • Keun-Sul Lee (Department of Science Education, Sang Myung Women College) ;
  • Kim Dae-Woong (Research Institute of Korea Chemical Co. Ltd.) ;
  • Myon-Yong Park (Department of Chemistry, Kon-Kuk University)
  • 정우태 (충북대학교 약학대학 화학과) ;
  • 이근설 (상명여자대학 과학교육과) ;
  • 김대웅 (고려화학 주식회사 중앙연구소) ;
  • 박면용 (건국대학교 문리과대학 화학과)
  • Published : 1982.10.30

Abstract

The fluorescence yields of chl-a and-b complexes bound to silicon dimer, tetramer and hexamer containing pyridine group in diethyl ether solvent, were shown the transition of excited energy through silicon polymer chain, and the maximum energy quenching were appeared at 1 : 1 ratio of chl-a and pyridine group in silicon polymer but the chl-b complexes were shown the maximum energy of fluorescene emission at the same ratio.

Chlorophyll-a(chl-a)와 chlorophyll-b(chl-b)를 pyridine을 포함한 실리콘의 dimer, hexamer에 결합시킨 물질은 중합체의 pyridine 농도와 chl-a의 농도의 비가 1:1일 때 가장 큰 에너지 전이를 나타냈으며 chl-b와 실리콘 중합체는 가장 큰 들뜬 에너지를 나타냈다.

Keywords

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