DOI QR코드

DOI QR Code

Kinetic Study on Bromine-Exchange Reaction of Antimony Tribromide with t-Butyl Bromide in Nitrobenzene and in 1, 2, 4-Trichlorobenzene$^*$

  • Choi, Sang-Up (Department of Chemistry, Sogang University) ;
  • Pae, Young-Il (Department of Industrial Chemistry, Ulsan Institute of Technology)
  • Published : 1982.12.30

Abstract

The kinetic study on the bromine-exchange reaction of antimony tribromide with t-butyl bromide in nitrobenzene or 1,2,4-trichlorobenzene has been carried out, using Br-82 labelled antimony tribromide. The results show that the exchange reaction is first order with respect to t-butyl bromide and 1.5th order with respect to antimony tribromide. It is assumed that the 1.5th order indicates the coexistance of first- and second-order kinetics. Reaction mechanisms for the exchange reaction are proposed.

Keywords

References

  1. Bull. Korean Chem. Soc. v.3 Sang Up Choi;Young Il Pae;Sok Hwan Rhyu
  2. J. Amer. Chem. Soc. v.87 Sang Up Choi;J. E. Willard
  3. J. Phys. Chem. v.72 Oh Chun Kwon;Sang Up Choi
  4. J. Korean Chem. Soc. v.14 Sang Up Choi
  5. J. Korean Chem. Soc. v.20 Oh Chun Kwon;Sang Up Choi
  6. Bull. Korean Chem. Soc. v.2 Oh Chun Kwon;Young Cheul Kim;Sang Up Choi
  7. Bull. Koeran Chem. Soc. v.2 Oh Chun Kwon;Young Cheul Kim;Sang Up Choi
  8. Young Il Pae;Sang Up Choi
  9. Nuclear and Radiochemistry G. Friedlander;J. W. Kennedy;J. M. Miller