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Lithium n-Butylborohydride. An Excellent 1, 2-Selective Reducing Agent of Conjugated Enones

  • Kim Sunggak (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Moon Young Choon (Department of Chemistry, Korea Advanced Institute of Science and Technology)
  • Published : 1982.06.30

Abstract

Lithium n-butylborohydride generated from n-butyllithium and borane-dimethyl sulfide complex in equimolar ratio in toluene-n-hexane is exceedingly effective for selective 1,2 reductions of enones.

Keywords

References

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Cited by

  1. Natural cyclic α, β-enone monoterpenoids in nucleophilic addition reactions vol.42, pp.4, 1982, https://doi.org/10.1007/s10600-006-0161-z