The Effects of Ferrous Ion on Properties of Bright Nickel Electordeposit

광택 니켈 도금속에 미치는 이가식 이온의 영향

The effects of ferrous ion on the properties of bright nickel electrodeposit were exa-mined. Iron exists as ferrous ion (Fe+2) and ferric ion (Fe+3) in the bath, a portion of the former tend to be oxidized to the somewhat harmful ferric ion. Iron was added to bath as the ferrous sulfate, ferrous ion prevented from the oxidation with citric acid. It was found that the hardness was increased as the concentration of ferrous ion, the ductility was slightly increased too. The appearance can obtain the wide bright deposits within 4g/$\ell$. The corrosion resistance drastically dropped from 5g/$\ell$ In the case of considering the effect of ferrous ion on the corrosion resistance and the appearance, the allowable limits is 4g/$\ell$, if the reductant is used.