Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Synthesis and Characterization of Substituted Pyridine Complexes of Molybdenum (II). Substituted Pyridinium Salts of Oxopentachloromolybdates (V)

몰리브덴의 피리딘계 착물합성과 그 성질 (제2보). 옥소오클로로몰리브덴 (V) 의 치환피리딘늄염

  • Sang Oh Oh (Department of Chemistry, Kyungpook National University) ;
  • Chang Su Kim (Department of Chemical Education, Hansa College)
  • 오상오 (경북대학교 문리과대학화학과) ;
  • 김창수 (한사대학 화학교육과)
  • Published : 1981.08.30
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Abstract

The substituted pyridinium salts of oxochloromolybdates(V) have been prepared characterized by visible and infrared spectra, and magnetic moments. The electrical conductance of aqueous solutions of substituted pyridinium salts have been measured over a range of concentrations. The results indicate that the complex anions are monomeric in the solid. The magnetic moments of the complexes are similar to the spin-only values. Substituted pyridines are present as pyridinium cation in solid state.

옥소오클로로몰리브덴(V)산의 여러가지 치환피리딘늄염을 합성하고 이들 착물의 흡수스펙트럼 및 자화율을 측정하였다. 수용액에서 착물의 전기전도도를 농도에 따라 측정한 결과 치환피리딘류는 양이온 상태로 존재하고 있으며 이들 착물의 자기모멘트는 ${\mu}_{spin-only}$와 거의 같았다.

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