Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis of Substituted Phenyltrichlorocyclopropene Derivatives Using Friedel-Crafts Reaction

  • Choi, Sam-Kwon (Department of Chemistry, Korea Advanced Institute of Science) ;
  • Suk ,Won-Kyung (Department of Chemistry, Korea Advanced Institute of Science)
  • Published : 1981.09.30
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Abstract

Tetrachlorocyclopropene has been prepared smoothly by the dehydrochlorination of pentachlorocyclopropane which could be obtained easily from sodium trichloroacetate and trichloroethylene in 1,2-dimethoxyethane. By the reaction of aromatic hydrocarbons with tetrachlorocyclopropene and aluminium chloride, new substituted phenyltrichlorocyclopropene derivatives have been prepared. The structures of these compounds were characterized by means of spectroscopic methods.

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  1. Trichloroethylene in organic synthesis vol.63, pp.8, 1981, https://doi.org/10.1070/rc1994v063n08abeh000109