Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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S$_N$2 Transition State Variation in the Benzenesulfonyl Chloride Sovolysis$^*$

  • Published : 1981.06.30
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Abstract

For solvolyses of benzenesulfonylchlorides we determined transfer enthalpies of transition states, and solvent (TFE + EtOH) and substituent effects on rates. We have used the More O'Ferrall plots to show that transition states variation caused by solvent and substituent changes is consistent with an associative $S_N2$ mechanism for the nucleophilic substitution reaction of benzenesulfonylchlorides.

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References

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