Abstract
The tendency of glass containing titanium-dioxide to separate into two phases can be attributed to a change of the coordination number of titanium from six to four on increase of temperature and to "freezing" of the high temperature four fold coordination on cooling of the melt. Addition of TiO2 to the basic glass 8.7 $Na_2O$ 22.4B2O3 68.9 $SiO_2$ was varied 5 to 25 parts. The phase separation in the temperature range of transformation was examined with each heating temperature and soaking time. As the experimental results, the most distinct phase separation were obtained from alkali extraction method when $TiO_2$ was added 15 parts. The apparant activation energy was 30.5 Kcal/mole by alkali extraction method derived from Arrhenius plots.ius plots.