Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Reactions of Organostannyl Compounds with Unsaturated Compounds

유기주석화합물과 불포화화합물과의 반응

  • Il-Kyu Lee (Department of Chemistry, Chung-Ang Univeristy) ;
  • Bae-Seok Seo (Department of Chemistry, Chung-Ang Univeristy) ;
  • Ghap-Ju Kim (Department of Chemistry, Chung-Ang Univeristy)
  • 이일규 (중앙대학교 문리과대학 화학과) ;
  • 서배석 (중앙대학교 문리과대학 화학과) ;
  • 김갑주 (중앙대학교 문리과대학 화학과)
  • Published : 1980.10.30
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Abstract

Trimethylstannyl-diethylamine, trimethylstannylethylsulfide, trimethylstannylmethoxide and trimethylstannylhydroxide were reacted with phenylisocyanate at various temperatures. The product was only triphenylisocyanurate below $100^{\circ}C$ and the mixtures of triphenylisocyanurate and diphenylcarbodiimide were obtained at $150^{\circ}C$. Whereas, in the reaction of trimethylstannyldiethylamine with chloral, N,N-diethylformamide and trimethylstannyltrichloromethide were produced. The products from the reaction of N-ethylhexamethyldistannazane with phenylisothiocyanate were bis(trimethylstannyl) sulfide and N-ethyl-N'-phenylcarbodiimide.

Trimethylstannyl-diethylamine, -ethylsulfide, -methoxide 및 -hydroxide 등과 phenyl-isocyanate를 여러 온도에서 반응시킨 결과, $100^{\circ}C$ 이하에서는 triphenylisocyanurate만이 생성되었고, $150^{\circ}C$에서는 triphenylisocyanurate 와 diphenylcarbodiimide가 생성되었다. 한편, trimethylstannyldiethylamine과 chloral과의 반응에서는 N,N-diethylformamide와 trimethylstannyltrichloromethide가 생성되었으며, N-ethyl-N'-phenylcarbodiimide가 생성하였다.

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