대한화학회지 (Journal of the Korean Chemical Society)

  • 제24권5호
  • /
  • Pages.356-360
  • /
  • 1980
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

Co(Ⅲ) Glycine Methyl Ester 착물에 관한 연구 (제1보). 착물의 합성과 구조규명

Co(Ⅲ) Complexes of Glycine Methyl Ester (Ⅰ). Preparation and Characterization

  • Ja Hong Kim (Department of Chemistry, Jeonbug National University) ;
  • Sang Chul Shim (Department of Chemistry, The Korea Advanced Institute of Science)
  • 발행 : 1980.10.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

팔면체 구조를 갖는 Co(Ⅲ) glycine methyl ester 착물을 합성하고 원소분석과 적외선 스펙트럼 및 핵자기공명스펙트럼을 이용하여, 이들 착물의 구조에 관하여 고찰하였다. 이들 중 $[Co(gly)_2(glycinemethylester)Cl]Cl_2$ 착물은 양이온 교환수지인 Dowex 50W-X8을 이용하여 분히하였으며, 가능한 기하학적 이성질체는 $C_1-cis(0-0), C_2-cis(0-0), trans(0-0)$ 형태의 구조를 가지고 있음을 확인하였다.

Octahedral Co(Ⅲ) complexes of the glycine methyl ester have been prepared and characterized by elemental analysis, infrared, and NMR spectrum. Co(Ⅲ) glycine methyl ester complex has been isolated from the reaction of glycine and glycine methyl ester in aqueous solution by cation exchange resin, Dowex 50W-X8 (hydrogen form). It has been observed that the complexes have $C_1-cis(0-0), C_2-cis(0-0), trans(0-0)$ geometry.

키워드

참고문헌

  1. Bull. Chem. Soc., Japan v.34 M. Mori;M. Shibata;E. Kyuno;M. Kanaka
  2. Inorg. Chem. v.5 D. Alexander;D. H. Busch
  3. Australian J. Chem. v.18 F. P. Dwyer;I. K. Reid;A. M. Sargeson
  4. Inorg. Chem. v.4 R. G. Asperger;C. F. Liu
  5. Bull. Chem. Soc., Japan v.45 M. Saburi;S. Yoshikawa
  6. Inorg. Chem. v.12 M. Goto;H. Matsushita;M. Saburi;S. Yoshikawa
  7. J. Korean Chem. Soc. v.15 M. J. Jun;C. F. Liu
  8. Bull. Chem. Soc., Japan v.40 N. Matsuoka;J. Hidaka;Y. Shimura
  9. Bull. Chim. Soc. v.49 N. Matsuoka;Y. Shimura
  10. Bull. Chem. Soc., Japan v.46 K. Yamanari;Y. Shimura
  11. Bull. Chem. Soc., Japan v.48 K. Kobayashi;M. Shibata
  12. Bull. Chem. Soc., Japan v.50 T. Ama;M. Higa;N. Koine;T. Yasuri
  13. J. Amer. Chem. Soc. v.87 J. F. Endicott;M. Z. Hoffman
  14. J. Amer. Chem. Soc. v.94 A. F. Vando;E. R. Katrowitz;M. Z. Hoffman;E. Papaconstantinou;J. F. Endocott
  15. Inorg. Chem. v.4 V. Balzani;V. Carassiti;L. Moggi;N. Sabbatini
  16. Photochemistry of Coordination Compounds V. Balzani;V. Carassiti
  17. J. Amer. Chem. Soc. v.67 J. C. Bailer;L. B. Clapp
  18. J. Amer. Chem. Soc. v.5 D. Alexander;D. H. Busch
  19. The Infrared Spectra of Complex Molecules L. J. Bellamy
  20. Bull. Chem. Soc., Japan v.40 N. Matsuoka;J. Hidaka;Y. Shimura