Bulletin of the Korean Chemical Society

  • 제1권1호
  • /
  • Pages.17-22
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  • 1980
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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The Importance of One-Eletron Effects in Conformation and Protonation of Acetamides $^*$

  • 발행 : 1980.03.30
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초록

The CNDO/2 method was used to compute relative stabilities of various configurations and conformations of acetamide, N-methylacetamide and diacetamide and their protonated forms. It was found that: (a) nonbonded interactions play important roles in determining structural preferences of the compounds, (b)$n-{\sigma}^{\ast}$ "throughbond" interactions always favor cis-protonation (relative to C-N).

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참고문헌

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