HMo Correlation Diagram for Photocyclization of o-Terphenyl Type Compounds

o-Terphenyl型 化合物의 光고리화反應에 대한 HMO 相關圖

  • Lim Yong Jin (Department of Applied Chemistry, College of Engineering Kyungpook National University) ;
  • Lee Kwang Jo (Department of Applied Chemistry, College of Engineering Kyungpook National University) ;
  • Park Byung Kak (Department of Chemistry, Young Nam University)
  • 임용진 (慶北大學校 工科大學 應用化學科) ;
  • 이광조 (慶北大學校 工科大學 應用化學科) ;
  • 박병각 (嶺南大學校 文理科大學 化學科)
  • Published : 1979.06.30

Abstract

The cyclization of o-terphenyl type compounds were interpreted by means of orbital symmetry theory and energy correlation diagram. Results show that the cyclization of o-terphenyl type compounds are photocyclization. This agrees with the experimental result and other theoretical ones.

o-Terphenyl형 화합물들의 고리화반응을 궤도대칭이론과 에너지 상관도로서 해석하였다. 그 결고ㅓㅏ o-terphenyl형 화합물들의 고리화반응은 광고리화반응이었다. 이것은 실험적 사실 및 타이론적 결과와 잘 일치하였다.

Keywords

References

  1. Bull. Chem. Soc. Japan v.44 T. Sato;S. Shimada;K. Hata
  2. Organic Photochemistry v.1 F. R. Stermitz;O. L. Chapman(Ed.)
  3. Quart. Rev. v.23 E. V. Blackburn;C. J. Timmons
  4. J. Amer. Chem. Soc. v.86 F. B. Mallory;C. S. Wood;J. T. Gordon
  5. J. Org. Chem. v.29 C. S. Wood;F. B. Mallory
  6. Bull. Chem. Soc. Japan v.40 T. Sato;Y. Goto;T. Tohyama;S. Hayashi;K. Hata
  7. Bull. Chem. Soc. Japan v.40 T. Sato;Y. Goto;K. Hata
  8. Chem. Comm. H. B. Lewis;W. Woff
  9. Bull. Chem. Soc. Japan v.42 T. Sato;S. Shimada;k. Hata
  10. Chem. Commum. T. Sato;S. Shimada;K. Hata
  11. Tetrahedron v.24 H. Gusten;L. Klasinc
  12. Rec. Trav. Chem. Pays-Bas v.87 W. H. Laarhoven;J. H. M. Cuppen;R. J. F. Niverd
  13. Bull. Chem. Soc. Japan v.45 T. Sato;T. Morita
  14. J. Korean. Chem. Soc. v.20 I. Lee;B. Lee
  15. J. Chem. Soc. (B) K. A. Muszkart;E. Fischer
  16. R. B. Woodward;Hoffmann
  17. Bull. Chem. Soc. Japan v.46 H. Fujinotr;M. Miyagi;S. Yamabe;K. Fukui
  18. J. Amer. Chem. Soc. v.87 R. B. Woodward;Hoffmann
  19. J. Chem. Soc. M. V. Sargent;C. J. Timmons
  20. J. Amer. Chem. Soc. F. B. Mallory;C. S. Wood;J. T. Gordon;L. C. Lindquist;M. S. Savitz