대한화학회지 (Journal of the Korean Chemical Society)

  • 제23권2호
  • /
  • Pages.115-118
  • /
  • 1979
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

비닐시클로프로판의 光化學反應에 관한 硏究

Photochemistry of Some Vinylcyclopropanes

  • Shim Sang Chul (Department of Chemistry, Korea Advanced Institute of Science) ;
  • Suh Shi Woo (Department of Chemistry, Korea Advanced Institute of Science)
  • 발행 : 1979.04.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

1,1-디페닐-2-비닐시클로프로판을 벤젠, n-헥산, 아세토니트릴에 녹여 253.7nm의 빛을 쪼이면 1,1-디페닐에틸렌이 주생성물로 얻어지며 4,4-디페닐시크로펜텐, 저분자량의 고분자 물질 및 미확인 생성물이 소량으로 얻어진다. 증감제를 쓴 광화학반응과 UV 흡광스펙트럼으로부터 시클로프로판고리가 비닐기나 벤젠고리와 어느 정도 걸러짝짓기를 하고 있으나 시클로프로판고리를 통한 걸러짝짓기는 일어나지 않는다.

The photochemical reactions and spectral properties of 1,1-diphenyl-2-vinylcyclopropane were studied. Upon direct irradiation of the compound at 253.7nm, 1,1-diphenylethylene was formed as a major product along with a small amount of 4,4-diphenylcyclopentene. Sensitized photoreactions showed quite a different phenomena from those of conjugated dienes supporting the spectral results that the cyclopropane ring does not transmit the conjugation in the compound.

키워드

참고문헌

  1. Russ. Chem. Rev. v.31 M. Lukina
  2. J. Chem. Soc. R. Kierstad;R. Linstead;B. Weedon
  3. J. Amer. Chem. Soc. v.81 S. Sarel;E. Breuer
  4. J. Amer. Chem. Soc. v.87 N. C. Deno;H. G. Richey, Jr.;J. S. Liu;D. N. Lincoln;J. O. Turner
  5. J. Amer. Chem. Soc. v.69 M. T. Rogers
  6. J. Amer. Chem. Soc. v.68 J. D. Roberts;C. Greene
  7. J. Amer. Chem. Soc. v.70 R. P. Mariella;L. F. Peterson;R. C. Ferris
  8. J. Org. Chem. v.21 M. F. Hawthorne
  9. J. Amer. Chem. Soc. v.72 J. F. Music;F. A. Matsen
  10. Bull. Soc. Chim. France S. S. Julia;M. Julia;S. Tchen;P. Graffin
  11. Bull. Soc. Chim. France S. Julia;M. Julia;P. Graffin
  12. Bull. Soc. Chim. France J. Pete
  13. J. Amer. Chem. Soc. v.85 D. J. Patel;M. E. Howden;J. D. Roberts
  14. Chem. Rev. v.69 H. M. Frey;R. Walsh
  15. J. Amer. Chem. Soc. v.76 R. H. Eastman
  16. J. Amer. Chem. Soc. v.81 G. W. Cannon;A. A. Santelli;P. Shenia
  17. J. Amer. Chem. Soc. v.80 E. N. Tsachtenberg;G. Odian
  18. The Chemistry of Alkenes v.II M. Charton;J. Zabick(ed.)
  19. J. Org. Chem. v.34 J. M. Stewart;G. L. Pagenkopf
  20. J. Korean Chem. Soc. v.22 I. Cho;K. D. Ahn
  21. J. Amer. Chem. Soc. v.99 N. Shimju;T. Fujioka;S. Ishizuka;T. Tsuji;S. Nishida
  22. Purification of Laboratory Chemicals D. D. Perrin;W. L. F. Armarego;D. R. Perrin
  23. Anal. Chem. v.37 no.9 J. F. O'Donnell;J. T. Ayres;C. K. Mann