Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지

Synthesis of Analcime from Domestic Bentonite

국산 Bentonite로부터 Analcime합성

  • 노훤주 (한양대학교 화학공학과) ;
  • 주충열 (한양대학교 화학공학과) ;
  • 김면섭 (한양대학교 화학공학과)
  • Published : 1979.04.01
Download PDF
⟨ Previous Next ⟩

Abstract

Domestic Yungil bentonite (montmorillonite) was treated with 1N sodium hydroxide solution in an autoclave at several temperatures, between 100 to 200℃, for 1 to 24 hrs. The products were examined by X-ray diffraction analysis. The following concecutive reaction was valid. montmorillonite→amorphous aluminosilicate→analcime The reaction rate constants k and k' at 200℃ were 0.35hr-1 and 0.22hr-1, respectively. The activation energies for the conversion from montmorillonite to amorphous aluminosilicate and from amorphous aluminosilicate to analcime were 10 kcal/mol and 12kcal/mol, respectively.

Keywords

References

  1. J. Amer. Clem. Soc v.78 no.5963 Crystalline Zeolite, I. The Properties of a New Synthetic Zeolite D.W. Breck;W.G. Eversole;R.M. Milton;T.B.Reed;J.L. Thomas
  2. J. Amer. Chem. Soc v.82 no.1041 The Structures of Synthetic Molecular Sieves L. Broussard;D.P. Shoemaker
  3. 日本工業化學雜誌 v.72 no.1044 2價金屬オンゼオライト觸媒によるトルニンの不均化およぴ?アルキル化反應 森田義郎;松本泰重
  4. 化學と工業 v.21 no.1287 接觸分解角ゼオライト觸媒 高橋活
  5. J. Amer. Chem. Soc v.78 no.5952 Crystalline Zeolites, Ⅱ. Crystal Structure of Synthetic Zeotite, Type A T.B. Reed;D.W. Breck
  6. Ind. Eng. Chem, Prod. Res. Develop v.10 no.43 Adsorption and Separation of Hydrocarbins on Mordenite Zeolites P.E. Eberly, Jr
  7. Ind. Eng. Chem. Prod. Res. Deveop v.10 no.375 Decomposition of n-and sec-Butyl Acetates on Synthetic Zeolites, Catalytic Activity and Aging T. Imail;R.B. Amderson
  8. 日本工業學化學雜誌 v.72 no.1044 Y 型 ゼオライトの水溶液からの 合成における生成機構 白畸高保;小林正洪;森川淸
  9. 화학공학 v.15 no.101 하동 Kaolin으로부터의 Zeolite 합성반응속도 鄭雨昌;권이열;金免燮