Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Platinum(II) Complexes of 2,2-bis(Methylaminomethyl)-1,3-dioxolane

2,2-비스(메틸아미노메틸)-1,3-dioxolane의 백금(Ⅱ) 착물

  • Moo-Jin Jun (Deparment of Applied Chemistry, College of Engineering, Kyungpook National University)
  • 전무진 (경북대학교 공과대학 응용화학과)
  • Published : 1978.04.30
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Abstract

The synthesis of a bidentate secondary amine ligand, 2,2-bis(methylaminomethyl-2,3-dioxolane(methylaminomethyl)-1,3-dioxolane(mexo) and the preparation of dichloro and trans-R-cyclohexanediamine platinum(II) complexes of this ligand are reported. The structures of the ligand and complexes prepared have been elucidated via elemental analyses, nmr, electronic absorption, and CD spectra.

새로운 두자리 아민리간드 2,2-bis(메틸아미노메틸)-1,3-dioxolane(mexo)가 합성되었고 이 리간드로부터 디클로로 및 trans-R-cyclohexanediamine(R-chxn) 백금(II) 착물이 합성되었다. 착물은 평면 사각형의 구조이며 원소분석, 핵자기공명, 흡수분광법 및 원편광이색성분광분석을 이용하여 리간드와 착물의 구조를 설명하였다.

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