Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Electric Conductance of Dilute Solutions of Alkali Chlorides in Acetone-Water and Formic Acid-Water Mixtures

아세톤-물 및 포름酸-물 混合溶媒中에서의 알칼리 鹽化物溶液의 電導度

  • Byung-Rin Cho (Department of Chemical Engineering, Inha University) ;
  • Yong-Ja Lee (Department of Chemical Engineering, Inha University) ;
  • Kwang-Ho Kim (Department of Chemical Engineering, Inha University)
  • 조병린 (인하대학교 공과대학 화학공학과) ;
  • 이영자 (인하대학교 공과대학 화학공학과) ;
  • 김광호 (인하대학교 공과대학 화학공학과)
  • Published : 1978.02.28
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Abstract

The electric conductances of dilute solutions of alkali chlorides (LiCi, NaCl, KCl, RbCl, CsCl) in a series of acetone-water and formic acid-water mixtures were determined respectively at $^30{\circ}C$. The results of the conductances of alkali chlorides in acetone-water mixtures were analysed by the Debye-Huckel-Onsager equation and the variations of limiting equivalent conductances with the compositions of acetone-water mixtures were explained in terms of selective solvation of electrolytes. The conductances of dilute solutions of alkali chlorides in formic acid-water could not be analysed because of the strong ionic atmosphere of solvent itself.

여러組成의 아세톤-물 및 포름酸-물 중에서 각각 알칼리鹽化物(LiCl, NaCl, KCl, RbCl, CsCl)의 稀薄溶液의 電導度를 $^30{\circ}C$˚에서 측정하였다. 아세톤-물 混合溶媒中에서의 알칼리鹽化物의 電導度의 結果를 Debye-Huckel-Onsager式으로 解析하였고, 溶媒組成에 따르는 極限當量電導度의 변화를 電解質의 選擇的 溶媒化現象으로 설명하였다. 포름酸-물 中에서의 알칼리鹽化物의 稀薄溶液의 電導度는 溶媒自體의 强한 이온雰圍氣때문에 그 변화를 比較解析할 수가 없었다.

Keywords

References

  1. J. Amer. Chem. Soc. v.79 R.M. Fuoss;C.A. Kraus
  2. J. Phys. Chem. v.65 J.E. Lind Jr.;R.M. Fuoss
  3. J. Phys. Chem. v.65 J.E. Lind Jr.;R.M.Fuoss
  4. J. Phys. Chem. v.66 J.E. Lind Jr.;R.M.Fuoss
  5. J. Phys. Chem. v.67 R.W. Kunze;R.M. Fuoss
  6. J. Phys. Chem. v.67 R.W. Kunze;R.M. Fuoss
  7. J. Phys. Chem. v.67 J.C. Justice;R.M. Fuoss
  8. J. Phys. Chem. v.76 T.H. Leong;L.A. Dunn
  9. J. Amer. Chem. Soc. v.81 F. Accascina;A. D'Aprano;R.M. Fuoss
  10. J. Amer. Chem. Soc. v.83 C.J. Hallada;G. Atkinson
  11. J. Phys. Chem. v.74 G. Pistoia;G. Pecci
  12. J. Phys. Chem. v.74 T.L. Broadwater;R.L. Key
  13. J. Phys. Chem. v.75 D.F. Evans;J. Thomas;J.A. Nadas;M.A. Matesich
  14. J. Korean Chem.Soc. v.20 B.R. Cho;Y.J. Lee;J.B. Kim
  15. J. Phys. Chem. v.72 J. Padva
  16. An Introduction to Electrochemistry S. Glasstone
  17. Langes Handbook of Chemistry
  18. J. Korean Chem. Soc. v.15 B.R. Cho
  19. J. Korean Chem. Soc. v.15 B.R. Cho;Y.J. Lee;I. Lee
  20. J. Phys. Chem. v.67 F.T. Tuan;R.M. Fuoss
  21. The Physicochemical Constants of Binary Systems in Concentrated Solutions v.4 J. Timmermans
  22. J. Korean Chem. Soc. v.13 S.K. Yoon;I. Lee
  23. Can. J. Chem. v.46 I. Lee;J.B. Hyne
  24. Physik. Z. v.24 no.185 P. Debye;E. Huckel
  25. Trans. Faraday Soc. v.23 L. Onsager
  26. J. Phys. Chem. v.33 P. Debye;H. Falkenhagen
  27. J. Amer. Chem. Soc. v.75 R.C. Miller;R.M. Fuoss
  28. J. Amer. Chem. Soc. v.75 F.M. Sacks;R.M. Fuoss