대한화학회지 (Journal of the Korean Chemical Society)

  • 제21권1호
  • /
  • Pages.44-52
  • /
  • 1977
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

透析法에 依한 이온量 및 分子量의 決定에 關한 硏究 (第4報). 比表面積 및 透析膜孔이 透析에 미치는 影響

A Study on the Determination of Ionic and Molecular Weight of Dissolved Substance by Dialysis Method (Ⅳ). Effects of Specific Surface Area and Pore Size of Dialysis Membrane on Dialysis

  • 신윤경 (서울大學校 工科大學 工業化學科) ;
  • 이전 (仁荷大學校 工科大學 窯業工學科) ;
  • 김태천 (서울大學校 工科大學 工業化學科)
  • Yun Kyoung Shin (Department of Chemical Technology, College of Engineering, Seoul National University) ;
  • Jhun Rhee (Department of Ceramic Engineering, College of Engineering, College of Engineering, Inha University) ;
  • Taechun Kim (Department of Chemical Technology, College of Engineering, Seoul National University)
  • 발행 : 1977.02.28
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

透析係數가 常數로서 나타날 수 있는 條件究明의 一環으로서 透析液 單位體積當의 透析膜面積인 比表面積과 透析膜孔의 크기가 透析에 미치는 영향을 究明하였다. 1回의 透析實驗에서 任意時間區間마다 任意부피의 透析液試料를 잇따라 菜取하는 方法(間歇試料菜取法이라 呼稱하기로 함)은 透析係數를 求하는 方法으로서 採擇할 수 있음과, 또한 透析膜孔이 상당히 크더라도 膜을 通한 擴散係數는 自由擴散係數에 미치지 못함을 밝히었다.

The effects of specific surface area and pore size of dialysis membrane on the dialysis were studied. It was confirmed that the intermittent sampling method(in which any volume of dialyzing solution is sampled intermittently at every moment after any duration of the dialysis experiment) is suitable for the determination of a dialysis coefficient. It was also confirmed that the diffusion coefficient of a electrolyte through membrane is smaller than the free diffusion coefficient though the pore size of dialysis membrane is extremely large.

키워드

참고문헌

  1. Z. anorg. u. all. Chem. v.168 H. Brintzinger(et al.)
  2. Z. anorg. u. all. Chem. v.172 H. Brintzinger(et al.)
  3. Z. anorg. u. all. Chem. v.184 H. Brintzinger(et al.)
  4. Z. anorg. u. all. Chem. v.196 H. Brintzinger(et al.)
  5. Z. anorg. u. all. Chem. v.228 H. Brintzinger(et al).
  6. Z. anorg. u. all. Chem. v.231 H. Brintzinger(et al.)
  7. Z. anorg. u. all. Chem. v.232 H. Brintzinger(et al.)
  8. Z.anorg. u. all. Chem. v.256 H. Brintzinger
  9. Z.anorg. u. all. Chem. v.168 H. Brintzinger
  10. Z. Elektrochem. v.51 K. E. Stumpf
  11. Zh. Fiz. Khim. v.35 L. B. Dvorkin
  12. J. Kor. Chem. Soc. v.16 Y. K. Shin;J. Rhee
  13. Instrumental Methods of Analysis H. H. Willard;L. L. Meritt, Jr.;J. A. Dean
  14. Volumetric Analysis, vol. III, Titration Methods I. M. Kolthoff(et al.)
  15. MF-Millipore Filter Catalog MC/1 Millipore Corporation
  16. J. Kor. Chem. Soc. v.18 Y. K. Shin;J. Rhee
  17. Dissertation, Inha University J. Rhee
  18. J. Amer. Chem. Soc. v.74 Julian M. Nielson(et al.)
  19. J. Amer. Chem. Soc. v.72 R. H. Stokes
  20. J. Kor. Chem. Soc. v.17 Y. K. Shin;J. Rhee