Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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A Synthesis of Tungsten Complexes with Oxine, Aniline or Pyridine in Organic Solvent

有機溶媒中에서 옥신, 아닐린 및 피라딘을 포함하는 텅스텐錯物의 合成

  • Doo Won Park (Department of Chemistry, College of Liberal Arts Science, Kyungpook National University) ;
  • Tae Sub O (Department of Chemistry, Teacher's College, Kyungpook National University)
  • 박두원 (慶北大學校 文理科大學 化學科) ;
  • 오대섭 (慶北大學校 師範大學 化學科)
  • Published : 1975.12.30
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Abstract

The insoluble tungsten complexes with 8-hydroxy quinoline (oxine=Hox), aniline (A), and pyridine(Py) in several organic solvents have been synthesized. Using the different solvents with oxine, two different complexes have been synthesized in dichloromethane and dimethylformamide(DMF), respectively. Only one kind of complex has been synthesized with aniline in dichloromethane and with pyridine in acetone. The complexes may be formulated as $WCl_2(Hox)_2,\;[WO_2(Ox_2)],\;[WCl_3A_3],\;and\;[WO_2ClPy]$ by the results of elemental analysis, infrared spectral data, and thermogravimetric analysis.

六鹽化 텅스텐(WCl6)을 여러가지 有機溶媒 속에서 리간드로서 옥신과 아닐린 및 피리딘을 각각 반응시켜서 不溶性인 텅스텐 錯化合物을 合成하였다. Dichloromethane과 DMF와 같이 서로 성질이 다른 溶媒속에서의 옥신 錯物을 合成해 보면 溶媒에 따라서 다른 錯物이 生成되었다. 아닐린의 錯物은 dichloromethane溶媒에서 合成되고 피리딘의 錯物은 아세톤溶液에서 合成되었다. 元素分析과 赤外線 스펙트럼 및 熱分析結果 錯化合物들은 組成이$[WCl_2(Hox)_2]와\;[WO_2(Ox)_2],[WCl_3A_3]\;및\;[WO_2ClPy]$임을 알아냈다.

Keywords

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