Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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A Study on the Tungsten (VI) Complexes with the Organic Acid Anhydrides

유기산 무수물을 리간드로한 텅스텐 (VI) 착물에 관한 연구

  • Sang-Oh Oh (Department of Chemistry, Kyungpook National University) ;
  • Kim, Chan Ho (Busan Custom House Laboratory)
  • Published : 1975.12.30
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Abstract

Dichloro-dioxo-tungsten(VI) complexes containing oxygen donor in anhydrous organic acid have been synthesized. Sodium tungstate reacts with acetylchlorides to produce the mononuclear complexes, yellow powder having $WO_2Cl_2(RCO)_2O$ as general formula. Their chemical properties and the possible structure are proposed by the results of spectral data and chemical observation.

Oxygen doner인 무수유기산을 가진 dichloro-dioxo tungsen(VI) 착물의 합성방법을 연구하였다. RCOCl과$NaWO_4$를 반응시켜서 일반식 $WO_2Cl_2(RCO)_2O$로 표시할 수 있는 황색분말인 단핵착물을 합성하고 그 성질을 고찰하였다. 이 새로운 착물의 구조를 스펙트럼과 화학적인 방법에 의하여 측정하였다.

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