대한화학회지 (Journal of the Korean Chemical Society)

  • 제19권5호
  • /
  • Pages.355-359
  • /
  • 1975
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

수소화붕소 아연에 의한 에폭시케톤의 선택환원

Selective Reduction of ${\alpha},\;[\beta}$-Epoxy Ketones with Zinc Borohydride

  • 윤능민 (서강대학교 이공대학 화학과) ;
  • 강재효 (서강대학교 이공대학 화학과)
  • Nung Min Yoon (Department of Chemistry, College of Science and Engineering, Sogang University) ;
  • Jahyo Kang (Department of Chemistry, College of Science and Engineering, Sogang University)
  • 발행 : 1975.10.30
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초록

에폭시케톤을 수소화붕소 아연으로 환원하면 카르보닐기만 선택적으로 확원되어 해당하는 에폭시알코올을 좋은 수득율로 얻을수 있음을 알 수 있었다.

Reduction of epoxy ketones with zinc borohydride proceeds selectively to the corresponding epoxy alcohols in good yields. Thus we obtained 3,4-epoxy-4-methyl-2-pentanol($79.8{\%}$), trans-isophorol oxide ($89.5{\%}$), trans-2-benzal-cyclohexanol oxide ($84.1{\%}$) and trans-chalcol oxide ($97.9{\%}$, crude) from the corresponding epoxy ketones.

키워드

참고문헌

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