Nuclear Engineering and Technology
- Volume 7 Issue 4
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- Pages.311-316
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- 1975
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- 1738-5733(pISSN)
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- 2234-358X(eISSN)
Nucleophilic Substitution at a Carbonyl Carbon Atom(VI)
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Lee, Hai-Whang
(Dept. of Chemistry, Inha University)
;
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Lee, Ikchoon
(Dept. of Chemistry, Inha University)
- Published : 1975.12.01
Abstract
Kinetic studies on the halide exchange reactions of substituted benzoyl chlorides have been carried out. The experimental result has been explained reasonably in terms of HSAB principle and EH-Theory, and addition elimination mechanism has been proposed for this type of reaction.
염화벤조일 치환체에 대한 할라이드 교환반응을 반응속도론적으로 연구하였다. HSAB 원리와 확장 Huckel 이론을 적용하여 실험 결과를 합리적으로 해석하였으며 이와 같은 유형의 반응에 대하여 첨가-제거 메카니즘이 합당함을 알았다.
Keywords