A Study on the Fluid Inclusions in the Minerals from the Dae Hwa Tungsten-Molybdenum Deposits

대화(大華) 중석휘수연광상산(重石輝水鉛床産) 광물중(鍵物中)의 유체포유물(流體包有物)에 관(關)한 연구(硏究)

Daehwa tungsten-molybdenum deposits is fissure filled quartz veins occurring in Precambrian granite gneiss adjacent to the contact with Mesozoic biotite granite mass. Essential ore minerals are molybdenum and wolframite accompaning scheelite, cassiterite, chalcopyrite, pyrrhotite, pyrite and bismuthinites. Gangue minerals are quartz and little muscovte, fluorite, beryl and Carbonate minerals. Fluid inclusions in quartz, fluorite, beryl, scheelite and calcite have filling temperature ranges of $170-353^{\circ}C$. According to the studies of mineral paragenesis and filling temperature of fluid inclusion indicate that main tungsten and molybdnum mineralization have taken place with the minerals whose filling temperature ranges 205 to $353^{\circ}C$. Liquid $CO_2$ bearing fluid inclusions are characteristic in the quartz and early fluorite of tungsten and tungsten bearing molybdenum veins but hardly recognized from molybdemun veins. Estimated $CO_2$ concentration according to diagram proposed by the Takenouchi ranges from 10 to 20wt%. These facts suggest that tungsten mineralization may be related to the $CO_2$ content of the hydrothermal solution during the mineralizing period.