Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Extended Huckel Calculations of the Effect of Sulfenyl, Sulfinyl and Sulfonyl Groups on the Reactivity of Halides in $S-N2$ Reactions

할라이드의 $S_N2$ 형 반응성에 미치는 술페닐, 술피닐 및 술포닐기의 효과에 대한 확장 Huckel 계산

  • Ui Rak Kim (Department of Chemistry, Catholic Medical College) ;
  • Kyu Yong Lee (Department of Chemistry, Catholic Medical College) ;
  • Sun Ho Bai (Department of Chemistry, Catholic Medical College) ;
  • Ikchoon Lee (Department of Chemistry, Inha University)
  • Published : 1974.02.28
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Abstract

Extended Huckel calculations have been carried out to study the effect of sulfenyl, sulfinyl and sulfonyl groups on the reactivity of halides in $S-N2$ reactions. Results indicate that the most reasonable reactivity index is that based on the Frontier electron for the bond formation process.

확장 Huckel법을 사용하여 술페닐, 술피닐 및 술포닐기가 할라이드의 $S-N2$형 반응에 미치는 효과를 고찰하고 각종 반응성 지수를 비교, 검토한 결과 bond formation과정의 반응성 지수중 Frontier electron에 의한 것이 가장 합리적인 것임을 밝혔다.

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