Nuclear Engineering and Technology
- 제6권1호
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- Pages.23-26
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- 1974
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- 1738-5733(pISSN)
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- 2234-358X(eISSN)
Nucleophilic Displacement of Sulfur Center, Part Ⅵ - Halide Exchange Kinetics of Methanesulfonyl Chloride in Acetone, Acetonirile and Methanol
- Lee, Ikchoon (Department of Chemistry Inha University) ;
- Yie, Jae-Eui (Department of Chemistry Inha University)
- 발행 : 1974.03.01
초록
염화 메탄 슬포닐의 할로겐 교환반응을 무수아세톤, 아세토니트릴, 메타놀 용매중에서 행하여 반응속도상수와 활성화파라메터를 구하였다. 친핵성도는 Cl->Br>I- 순서로 감소하였으며, 용매변화에 따른 염소이온과의 반응 속도는 (
The rates and activation parameters for the halide exchange reactions of methanesulfonyl chloride in dry acetone, acetonitrile, and methanol have been determined. It was found that nucleophilic order is Cl->Br->I-. The rate of chloride exchange with methanesulfonyl chloride decreases in the order of solvent; (
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