Role of Added Metal Oxide in the Adherence Mechanism of Low Melting Glass to Several Metal Seals

저융점유리와 각종금속과의 봉착기구에 있어서 금속산화물의 역할

  • 정창주 (전남대학교 요업공학과)
  • Published : 1974.03.01

Abstract

The role of added metal oxide in the adherence mechanism of low melting glass to several metal plates such as oxygen free high conducting copper, low carbon steel, chrominum galvanized on copper, and stainless steel was investigated. The metal oxide which added to glass were cupric oxide, ferric oxide, chromic oxide, and stainless steel oxide. The glass to that various metla oxide were added, sealed with several metal plates in the electric furnace at $650^{\circ}C$ for 5 minutes. The results as follows; 1) The interfacial reaction was promoted and strong chemical bonding with glass and metals by which the surface energy was decreased showed excellent sealing by addition of metal oxide. 2) When the interfacial reaction of glass and metals was promoted by addition of metal oxide found out that various adhernece mechanism were related to the sealing. 3) When the amount of metal oxide addition was 3-5% the excellent sealing was achieved.

Keywords

References

  1. J. Am. Ceram. Soc. v.44 no.9 Fundamentals of Glass to Metals Bonding Ⅶ, Wettability of Iron by Molten Sodium Silicate Containing Iron Oxide R.B. Adams;J.A. Pask
  2. Soc. of Glass Tech. Glass to Metal Seals J.H. Partridge
  3. Ceram. Bull. v.38 no.6 A Survey of Ceramic-to-Metal Bonding G.R. Von Houten
  4. J. Am. Ceram. Soc. v.49 no.1 Role of Adherence Oxides in the Development of Chemical Bonding at Glass-Metal Interfaces P. Coster
  5. J. Am. Ceram. Soc. v.45 no.12 Fundamentals of Glass-to-Metal Bonding:Ⅷ, Nature of Wetting and Adherence J.A. Pask;R.M. Fulrath
  6. 日窯協 v.72 no.2 ガラスと金屬の封着の機構 池田 豊
  7. 日窯協 v.74 no.10 ガラス對金屬封止における接觸機構 鮫島 治;西山雅男
  8. Advances in Glass Technology: (Ⅵ) International Congress on Glass F.D. Gaides;J.A. Pask
  9. Metals Handbook Tayler Lyman
  10. Metal Handbook Tayler Lyman
  11. ガラス工學 成瀨省
  12. Ceram. Bull. v.35 no.3 Role of Surface Energies and Wetting in Metal-Ceramic Sealing W.D. Kingery
  13. J. Am. Ceram. Soc. v.37 no.1 Metal-Ceramic Interaction;Ⅲ, Surface Tension and Wettability of Metal-Ceramic Systems M. Humenik;W.D. Kingery
  14. 日金屬學會誌 v.36 no.11 封着用 Fe-42Ni-6Cr合金の高溫酸化 久世孝;岩井直次;平澤康伸
  15. 日金屬學會誌 v.37 no.3 封着用 Fe-42Ni-6Cr 合金の高溫酸化と ガラス封着性に およぼす 添加元素の影響 久世孝;岩井直次;幕內昭司
  16. 日金屬學會誌 封着用 Fe-18Cr 合金の 高溫酸化と ガラス封着性 久世孝;岩井直次;幕內昭司
  17. 化學便覽 日本化學會編
  18. J. Am. Ceram. Soc. v.37 no.12 Metal-Ceramic Interaction;Ⅲ. Surface Tension and Wettability of Metal-Ceramic Systems G. Economos;W.D. Kingery