Synthesis of Cyclitol Derivatives (IV) Electrolytic Reduction of DL-epi-inosose-2

Cyclitol 유도체 합성에 관한 연구 (제4보) DL-epi-inosose-2의 전해환원

  • Sohn, Joo-Hwan (Department of Chemical Engineering, Inha Institute of Technology) ;
  • Nam, Chong-Woo (Department of Chemical Engineering, Inha Institute of Technology) ;
  • Park, Heung-Cho (Department of Chemical Engineering, Inha Institute of Technology)
  • 손주환 (인하공과대학 화학공학과) ;
  • 남종우 (인하공과대학 화학공학과) ;
  • 박흥조 (인하공과대학 화학공학과)
  • Published : 1972.04.30

Abstract

To obtain the various kinds of inositol stereomers, we have selected the process of electrolytic reduction of DL-epi-inosose-2 using Ni, Ta, Cu, Mo, Pb, Sn, W, Cd and Hg etc., as cathode. We think that this process gives greater variety than chemical processes. DL-epi-inosose-2 was synthesized by chemical oxidation of myo-inositol, dissolved in aqueous solution of potassium hydroxide, and used as electrolytic solution. To prevent anodic oxidation of cathode products the H-type diaphragm cell was used. As the results of paper chromatography of cathodic products, we obtained the $R_f$ values of myo-inositol and epi-inositol were in good agreement with literature values.

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References

  1. 대한화학회지 v.15 손;남;김
  2. Ber. v.45 J. Tafel
  3. Bull. Chem. Soc. Japan v.28 B. Sakurai;T. Arai
  4. J. Amer. Chem. Soc. v.80 L. Mandell;R.M. Powers;R.A. Day, Jr.
  5. Helv. Chim. Acta v.40 D. Reymond
  6. J. Chem. Soc. D.H.R. Barton
  7. Compt. Rend. v.225 P. Anziani;A. Aurry;R. Cornubert
  8. Helv. Chim. Acta v.19 T. Posternak
  9. Ber. v.46 Kaufmann;Valette
  10. Anal. Chem. v.23 G. R. Lappin;L.C. Cark
  11. Ber. v.86 K. Heyns;H. Paulsen
  12. nature v.166 W. E. Trevelyan;D.P. Proctor;J.S. Harrison
  13. J. Chem. Soc. S.J. Angyal;D.J. McHugh;P.T. Gilham
  14. Helv. Chim. Acta v.33 T. Posternak
  15. J. Chem. Soc. S.J. Angyal;D.J. McHugh
  16. 한국농화학회지 v.13 no.3 손
  17. J. Amer. Chem. Soc. v.48 Kunz;Hudson