대한화학회지 (Journal of the Korean Chemical Society)

  • 제15권6호
  • /
  • Pages.324-329
  • /
  • 1971
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

전착과산화납양극에 의한 옥소산염 전해산화

Anodic Oxidation of Iodate to Periodate by Lead Peroxide Anode

  • Chong Woo Nam (Department of Chemical Engineering, Inha Institute of Technology) ;
  • Hak Joon Kim (Department of Chemical Engineering, Inha Institute of Technology)
  • 발행 : 1971.12.30
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초록

In order to evaluate the mechanism of electrolytic oxidation of iodate and to determine the optimum conditions for the electrolysis, studies were made using the cells without diaphragm and the lead peroxide anode. Results are summarized as followings: 1) Current density vs. anode potential curve by lead peroxide electrode had the different limiting current densities from platinum electrode and was more positive than platinum electrode. 2) Additions of potassium bichromate in the electrolyte contribute to maintain high current efficiency. 3) In the acid and alkaline regions, the current efficiencies decreased by reduction of iodate and discharge of hydroxyl ion, so maximum current efficiency was shown at pH 7. 4) Higher current density lowered the current efficiency in the region of 60-80% conversion of iodate. 5) Influence of the conversion on current efficiency in the region of 60-80% conversion of iodate.

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참고문헌

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